Web Browser, Mail and Chat Preferences always revert to default on restart

I have set my prefs to Adium for chat, Firefox for web and Thunderbird for Mail - however - each time I restart my machine - they always revert to iChat, Safari and Mail.
I've deleted the relevant pref files but it still happens.
I'm also using filevault if this makes a difference.
Any clues?
Thanks.

The best place to ask that question is in the Mac OS 10.5 forums here:
Mac OS X v10.5 Leopard
Issues with Mail will get more eyes on the problem there than in the current forum, which tends to be more about hardware issues.
When you get there, searching for Mail issues is easily done by using the "Refine this List..." button in the upper part of the page. Click it and a number of sub-categories appear, one being "Mail & Address Book."
If you don't find a solution in existing posts. then ask you question, being sure that "Mail" appears prominently in the title, just like you did here.

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