When using Adobe Colour in Photoshop, Why can I not pick out colours from an image open and first up in Photoshop?

Am I doing something wrong?  Seems like it should be a no brainer, click for the color dropper and pick up a color.. seems I'm the one with the no brain thought because for the life of me it will not work. Then I would always go to colour Lovers and just upload my image and take the readings and put my theme together there.

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