Whenever I connect my iPhone 4s to my Windows 8.1 pc with iTunes 10.6.3.25, the iTunes freezes.

Whenever I connect my iPhone 4s to my Windows 8.1 pc with iTunes 10.6.3.25, the iTunes freezes and the only way to proceed is to kill the task under task manager. I have uninstalled iTunes following the recommended order and reinstalled numerous times but still freezes when I connect my iPhone. It works fine when I connect my phone to another pc (Windows 7). What else can I try?

Whenever I update iTunes it gives me the following error:
The application was unable to start correctly (0cx0000142). Click Ok to close the application.
The file in error is DifXInst64.exe.
Thanks for any more help available.

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