Why can't I export PDF files?

I'm trying to create a new library from several smaller libraries and have come across a problem where PDF files aren't included in my library export (File-Library-Export library). The music and video files on the other hand are all intact.
Trying to troubleshoot the issue I created a playlist with just the PDF files which I then tried to export (File-Library-Export playlist), saving as XML, which (when viewed in TextEdit) revealed that none of the PDF files were shown. Next I tried to add a single MP3 file in that playlist, did a new playlist export and viewed the XML file in TextEdit. This time I was able to see an entry for the MP3 file, but again nothing for all the PDF files.
I've also tried changing the Media kind (File-Get info, then choose the "Options" tab) between "Book" and "Music". Upon a second inspection ("Get info") it appears nothing was changed, but apparently something changes as the PDF files appear either in the "Music" or the "Books" library section. But unfortunately changing the media kind doesn't solve the problem of PDF files being un-exportable.
So is this a bug or perhaps even a copy protection scheme preventing copying of ebooks? (note: all my PDF files have been made by myself, so this is not copyrighted/purchased material)
iTunes 9.2.1, Powerbook G4, MacOSX 10.4.11

Some things you could try...
Using Windows Explorer navigate to C:\Program Files (x86)\Adobe\Reader 11.0\Reader, then double-click on Eula.exe and accept the license agreement
Can you open Adobe Reader by itself?  If so, try disabling Protected Mode [Edit | Preferences | Security (Enhanced)].
It could even be a malware issue; see http://helpx.adobe.com/acrobat/kb/reader-core-dll-error.html

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