Wrong Photoshop Elements catalog in iTunes to sync with iPhone

Hi,
I am using windows XP, latestversion of iTunes and Photoshop Elements 5 (PSE5).
I use several catalogs, one per each company I work for, and one entirely for personal pictures. The personal pictures catalog is the one I want to have automatically synchronized with iPhone, however, even though it is the "active" catalog that opens by default in Photoshop Elements, iTunes detects an other catalog and I want to change this so iTunes refers to the correct catalog. I tried restarting the PC after loading the desired catalog in PSE5 and closing it, and iTunes still refers to one of my work catalogs that I don't wish to use.
Any clue how to do this.
I could of course, have iTunes point to a specific folder, export the images from my personal catalog to that specific folder and do so every time I need to add pictures to my iPhone. This involves doing the image export and transfer manually every time, instead of automatically having the desired images added to the iPhone during sync, after they were tagged in PSE5 with the appropriate tag.
Thanks!
AB

Hi there.
Thanks for the response. Just to clarify, what is this and where can I find it? Finder Help had nothing to say about it, and Google just led me to this page:
http://support.apple.com/kb/HT1865
which strongly recommended me not to mess with it.
I really do need to make this old email account go away, I just need to make sure that I don't make the problem worse in the process. Thanks in advance for any help, just want to be extra careful here.

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