XMLDocument.Validate works on some machines but not on others

Hi All
I have a problem which I cannot Solve ,  I have a routine that Validates a node in a document  against a XSD file using the XmlDocument.Validate  method. This works fine on several machines but on a different network using the Same Document and schema files validate fails  with a validation exception element not found . I cannot figure out why the exact same files and application should be successful on one machine and unsuccessfull on another. I have used Filemon to see if their are ACCESS DENIED problems but there are none.
I have reinstalled the framework 2.0, to no avail
Regards

I am trying to Get the Details on to an HTTP server no luck yet,  and this fourm says that the files are to large to upload. , I have noticed the FILEMON says that the MSCORLIB.PDB file was not found in two locations WINNT and WINNT\dll  would this have somthing to do with the problem. I have given the XML and Schema files to others to view but they confirm that there is nothing wrong with the file or the schema.   

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