Buyer not appearing in the Approver LOV for a PO

Hi,
When submitting a Standard PO for Approval, my name(Buyer) was not visible in the Approver drop down list. It should have been there, and was there all last week. But today it was gone.
This happens intermittently and if I close all IE sessions and clear all cookies and temp files, it comes in the Approval list.
What could be the possible reason for this and permannent solution if any?
Quick help would be highly appreciated.
Thanks

1) I add a document to a library hosted in the Content Type Hub ....
Ok I create my library in my other HNSC and upload a test document which I attach to the same Content Type as above  .....
Spot the difference!!!!!
Freelance consultant

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