When I use Preview my computer locks up. Can't use it to view PDFs. Any ideas?

When I use Preview my computer locks up. Can't use it to view PDFs. Any ideas?
I try to save files as a PDF on external hard drives. When I select SAVE AS PDF I get spinning colorwheel and the program I am using locks (Quicken, Quickbooks, Gmail etc.)

There were several /Library/preferences. The only one that had the file was the one under my user name. I deleted it. I was using Quickbooks when the problem started. It is locked. I have to reboot the computer to use it again. I tried SAFARI using the PRINT button then SAVE AS PDF. It didn't work. It locks Safari up. I will reboot and hopefully continue.
P.S. I've done this procedure before and I was able to Save, but then the problem came back.

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