Authentication error when sending email from workflow but list alters email work fine

I have a list. When a user enables alert on this list then he/she is able to receive email from SharePoint when someone adds a new item or change item.
But emails sent by SharePoint workflow or Nintex workflow are not being sent. Error is:
Error 530 5.7.1 Client was not authenticated
Why emails are not being sent by workflows?
EDIT
And by SharePoint workflow, I mean OOB Publishing workflow.

Hi Frank,
For solving your issue , you can do as the followings:
1. Check all the email addresses are valid and they are not blocked by your SMTP admin
2. Check firewall settings if emails are blocking by any firewall or antivirus
3. You need to also check SPLog file if anything log there
4. Also create simple workflow with SharePoint Designer 2013, and give proper email to check whether it is working or not
Here is a similar article for you to take a look at:
http://techsuite.wordpress.com/2008/12/08/workflow-history-the-email-message-cannot-be-sent-make-sure-the-outgoing-email-settings-for-the-server-are-configured-properly/
I hope this helps.
Thanks,
Wendy
Wendy Li
TechNet Community Support

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