Can't send email via smtp on non- iCloud account

I can send email fine via the iCloud but when trying to send using a different account via smtp it does not work and places the email in the outbox. I hope I have explained this correctly and look forward to a response, thanks

I have an orange email account set up in addition to the iCloud .me account. When I am  in the orange email account on the apple mail program and try to send an email, it will not let me.
Thanks for your time so far
Edenr1

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