Setting up multiple from Accounts

Sorry for the poor title.
Small company with one Exchange server running 2010, users are using Outlook 2010, users eith use one of two domains depenpeng what part of the company they are in.
Example email addresses might be  [email protected]  and   
[email protected]
Now along comes user25 who had an email address od
[email protected] but now requires an email address in the billy domain as well so that he can reply to emails from either address and receive emails to one in box.
So I set user25 with an email alias in Exchange server 2010 his properties of [email protected]
Then followed the instructions to set up a dummy pop3 account on his client outlook application but this all failed to work.
Can anyone tell me the correct way to achieve this, do I need to tell the exchange server that a pop3 dummy account has been added to the clients properties?
Help please
Mark.

The easiest way to handle this is to create a distribution group for one mailbox, and set that mailbox so it can send from the distribution group.  In your example above,
[email protected] needs a second email address, so you create a distribution group with the email address
[email protected], and only Stuart's mailbox is a member of it.  Then you grant Stuart's mailbox rights to send from this distribution group (using the same commands you would for a mailbox, as follows:
Add-AdPermission <distribution group alias> -User <mailbox alias> -AccessRights ExtendedRight -ExtendedRights 'send as'
Then, in Outlook, add the From field to the messages and add the distribution group as a valid From sender and you are set.  The user will need to determine from the messages which address they need to respond from, though.

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