I accidentally hit "download all" in itunes on my iphone 5. Is there a way to stop this without going thru each song individually and pausing it?

I am new to the iphone, just got my 1st one today! 
I was just going to let the songs download, but shortly into it I got a message saying I had used 50% of data plan for MONTH, so I panicked and was just pausing each song as it started downloading.  There's several hundered songs.  Then I got a message saying I had used 75% data!  I turned on my airplane mode to stop everything.  Is there an easy way to stop the songs from ALL downloading without going thru each one individually?  I'm not very tech saavy, so please be nice and use small words...  Thanks.

Syncing shouldn't trouch you photos unless you have photos in a Photo Library album.  These would be photos that were synced to your phone from your computer.  If you do have any, you'll need to use an app like PhotoSync to transfer them to your computer prior to syncing.
If you prefer to backup your camera roll photos prior to syncing, open iTunes and go to Preferences>Devices and check "Prevent...from syncing automatically".  Then connect your phone to your computer and import them as explained here: http://support.apple.com/kb/HT4083.
Then, to minimize data loss, follow the steps in this user tip: https://discussions.apple.com/docs/DOC-3141.  To follow the steps, first open iTunes and go to View>Show Sidebar.  Also, Transfer Purchases is now located in File>Devices.

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