I've installed photoshop trial via cloud but can't run it

hi,
i've just installed a trial version of adobe photoshop but when i click on the desktop icon to "run" the program it doesn't work and instead i get this message :
"adobe-photoshop-cc-14.2.exe is not a valid Win32 application"
if anyone could offer suggestions to help me run this program that would be great. i'm using windows 7 professional on a new Dell PC.
thanks
margaret   

thanks for your help Mylenium - much appreciated
i'm a novice with technology - on a steep learning curve as they say - so don't know what "critical system DLL" is, but i do have AVG installed and seem to remember that i can add exceptions to sites that are blocked, so i'll try that route first.
thanks once again for your imput
Margaret

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