Outlook does not connect to Exchange 2013 after name change due to marriage

When launching Outlook and clicking through the setup wizard to create a new profile, Outlook auto-discovers the correct email alias. When establishing a connection it successfully checks network connectivity and successfully searches the email settings.
When it attempts to logon to the mail server the error comes up.
"The connection to Microsoft Exchange is unavailable. Outlook must be online or connected to complete this action."
Clicking "Check Name" gives the error:
"The name cannot be resolved. The connection to Microsoft Exchange is unavailable. Outlook must be online or connected to complete this action."
The same result occurs with a manual setup.
We are running Exchange Server 2013. User workstations are running Outlook 2013 on Windows 7 Pro. All updates have been applied as of March 31, 2015.
All name changes have been made in AD and Exchange. Old aliases and new aliases are set in Exchange. Offline Address books are updated daily. The local profile and registry settings have been updated on the workstation and the user is successfully logging
into the profile. The issue is only with Outlook 2013. User can access mail through OWA and ActiveSync on their mobile device.
Logging the user into another workstation and running the wizard returns the same results, which rules out the possible problem being with the workstation.

Hi,
According to your description, I understand that failed auto-configure Outlook with error “The name cannot be resolved. The connection to Microsoft Exchange is unavailable…”, however OWA works fine.
If I misunderstand your concern, please do not hesitate to let me know.
Are all account or any special user experience this question?
If OWA works fine, it indicate that the mailbox database is mounted, and mailbox works well.
I notice that you have changed the account name before issue arise, because external access, the client locates the Autodiscover service on the Internet by using the primary SMTP domain address from the user's email address.
More details about Autodiscover service, for your reference:
https://technet.microsoft.com/en-us/library/bb124251.aspx?f=255&MSPPError=-2147217396
Please try below command to force update address list, GAL, OAB, then test again:
Get-AddressList | update-AddressList
Get-GlobalAddressList | update-GlobalAdressList
Get-OfflineAddressBook | Update-OfflineAddressBook
If the issue persists, please wait for some time to complete configuration.
Thanks
Please remember to mark the replies as answers if they help, and unmark the answers if they provide no help. If you have feedback for TechNet Support, contact [email protected]
Allen Wang
TechNet Community Support

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    Test steps
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    Test steps
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    Fqdn                                 : EXCHANGE13.domain.local
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    OutlookAnywhereEnabled               : True
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    AutoDiscoverServiceClassName         : ms-Exchange-AutoDiscover-Service
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    AutoDiscoverServiceGuid              : 77378f46-2c66-4aa9-a6a6-3e7a48b19596
    AutoDiscoverSiteScope                : {Nombre-predeterminado-primer-sitio}
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    WorkloadManagementPolicy             : DefaultWorkloadManagementPolicy_15.0.825.0
    Identity                             : EXCHANGE13
    IsValid                              : True
    ExchangeVersion                      : 0.1 (8.0.535.0)
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    Groups,CN=First Organization,CN=Microsoft
                                           Exchange,CN=Services,CN=Configuration,DC=domain,DC=local
    Guid                                 : e83055fe-217b-4ed6-9cd0-7711097baf99
    ObjectCategory                       : domain.local/Configuration/Schema/ms-Exch-Exchange-Server
    ObjectClass                          : {top, server, msExchExchangeServer}
    WhenChanged                          : 09/03/2014 12:46:07
    WhenCreated                          : 08/03/2014 19:15:54
    WhenChangedUTC                       : 09/03/2014 11:46:07
    WhenCreatedUTC                       : 08/03/2014 18:15:54
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    ObjectState                          : Unchanged
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    Winnie Liang
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