Trying to SEND in Mail from email addresses not from my ISP verizon

I have Verizon fiber optic. All is okay except, I can't SEND from Apple's Mail program, when I try to send from an email address that I set up elsewhere. Receiving is fine. Just sending doesn't work. Verizon tech support worked with me for 2 hours with no success. the @verizon email addresses receive AND send, just not SENDING by way of my other POP accounts, which according to my web host should work.
I thought Mail could do this. Am I wrong?
Any help is appreciated.
Mail, version 1.3.11

What doesn “I can't send” mean? What’s the problem exactly? What error messages do you get, if any?
In an attempt to fight spam, many ISPs restrict the ability to send using an outgoing (SMTP) server not owned by them, usually by blocking port 25 for all traffic outside their own network, which means you cannot send with an SMTP server not owned by them if configured to use that port number. And it may happen the other way around as well, i.e. the outgoing server itself may look at the IP address you’re connecting from and refuse the connection if you’re outside its own network.
Something that often works is changing the outgoing server port to 587 (or whatever alternate port number the outgoing server listens to) instead of 25 and using some form of authentication in Preferences > Accounts > Account Information > Outgoing Mail Server > Server Settings, but two conditions must be satisfied for this change to work: (1) the ISP must not block that port as well AND (2) the outgoing server in question must listen to that port and accept a form of authentication not based on the IP address you’re connecting from.
Independent mail service providers not tied to a particular ISP, such as .Mac and Gmail, do allow authenticated SMTP access on port 587, which is the reason changing the outgoing server port number solves the problem for them if the ISP doesn’t block that port as well.
Read the following article, which applies to all versions of Mac OS X (not just Mac OS X 10.4.2 and earlier as the article states) and can be useful for other mail accounts as well (not just .Mac):
.Mac: Server timeout alert message when sending email

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