Why do my images become very desaturated and the exposure changes every time I paste them to a blank page? The originals are so vibrant and warm by comparison.

Hi,
For work I always paste 3 images of varying sizes onto the same page in photoshop. This wasn't an issue and always looked great when I did it in ps5, but since upgrading to ps6 they always paste flat, desaturated and underexposed. Put side-by-side with the original they look terrible. 
This is something I desperately need to resolve as I show this small collection to my customers and potential customers.
I've changed my color settings in an attempt to sort this out, but this has made absolutely no difference.
Thanks in advance
Kimberly

RGB is not a color space, it's a color model. Color spaces are sRGB, Adobe RGB, ProPhoto RGB etc.
Since you're apparently not familiar with these concepts, you should work consistently in sRGB, which displays roughly right in all scenarios even in the absence of color management.
The default color space out of Lightroom (if you haven't changed it) is ProPhoto, which can quickly get you into trouble unless you know what you're doing. Change it to sRGB in Lr Preferences > External editing.
Don't change Photoshop color settings! That will quickly get you into an even bigger mess than you are now. Reset it to default settings and don't touch them again until you know more. What you need to change is Lightroom "Edit in Photoshop" color space.

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