You can't open the application "MFI_Simulator.exe" because Microsoft Windows applications are not supported on OS X. Can someone assist. I have Office for Mac 2011 on MacBook Pro 13''.

You can’t open the application “MFI_Simulator.exe” because Microsoft Windows applications are not supported on OS X. Can someone assist. I have Office 2011 on my MacBook Pro, OS X, 10.9.1.

Your Office 2011, though a Microsoft product, is designed to work with OSX the Mac operating system.  Any program/application ending .exe is an executable program for Windows.  It will only work in Windows and is not part of or openable with Microsoft Office.
the application you want to open needs Windows - you have a couple of alternatives:
Open it on a Windows PC
Install a valid version of Windows via Bootcamp (or Parallels or VM Fusion) which will allow you to boot your Mac into Windows where it will function like a Windows PC and you can use it to run the application.
See if the manufacturers of MFI_Simulator have a Mac version available.
Please note that if you follow the second option, then you will need to purchase a copy of Windows (if you do not have one already). BootCamp is free (part of OSX) but Parallels and VM Fusion cost too.  I see quite a few posts from people who buy Parallels and try to run the program under Parallels - this doesn't work - you need to install Windows as well.
Hope this helps.

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