"Can't open a scratch file" error

Running PSD 12.0.4 (Extended) on a Mac Pro, Mac OS 10.7.3. Plenty of ram; plenty of hard disk space.
I just finished installing a new 1TB drive in one of my bays; I now have (3) 1TB drives total. Initialized the new drive (Mac OS Extended/Journaled), partitioned for Lion, then installed the OS and migrated everything from my primary (boot) drive using Migration Assistant.
After finishing, PSD gives the following error on start: "Could not open a scratch file because the disk is not available". I can command+option on start, select the boot drive as scratch and set the rest to None; that configuration works (and sticks). However, if I try to set scratch volumes to either of my backup volumes, I get the same error. Additionally, Illustrator can't even see the other two volumes in the scratch disk selector (PSD sees them, but won't accept them).
Here's what I've done:
- using simple disk drive names (i.e. WD1, WD2, WD3)
- verified all drives with Disk Utility
- ran drive diagnostics on all drives using SMART Utility (no problems found)
- reset paramter ram (comand+option+p+r on Mac startup)
- repaired permissions (all volumes - no permission errors found)
- reset PSD prefs (command+option+shift on start)
- deactivated/uninstalled/reinstalled PSD
At this point, I'm stumped. This must be related to having installed the new hard drive (everything was fine prior to that), but I don't know what else to try at the moment.
Anyone have any ideas?

Please read my original post (bullet item 6).
General comment - if you aren't going to give the original, detailed description a focused reading, then please don't post a reply. I haven't got the time to answer answered questions.
Also - no bragging intended - I am a Mac guy. I know the platform well, so anyone who wants to offer a Mac-related observation can assume I know what I'm doing and talk on an advanced level.
One additional observation - the problem persists when logged in under a different user account.

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