Cannot send mails with second Account

Hi,
I have 2 Mail-Accounts.
Account_A(mobileme) and
Account_B(exchange)
In the Account settings I have associated both Accounts to use there own SMTP. If I try now to send a mail with Account_B i directly become an error that the mail cannot be send over the server_B. If I hit "check connections" everything wents green, which implicates, that everything should be fine.
Now comes the funny part: In the same error Window there is a message: Send from: Account_A!
Any idea to get this working?
Info:
Yes. The settings in "Compose message" are right
Yes. Both Accounts are setup correct and work fine with iPhone and iPad
Thanks, Michael

What error message do you receive when try to send from Account_B?

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