Site access request alerts are not being sent to specified email.

In my SharePoint 2013 deployment I can't seem to get access request alerts working correctly. I go into the site permissions for any given site, enable access request and set an email address. When a user requests access an email is never sent to the address
i specified. Because of this site administrators have to constantly go into the site settings and check if there are any access requests and approve or deny them. I have checked my Exchange server logs and no email ever reaches it so it appears the alert is
never generated. Other outgoing emails such as alerts on libraries do work correctly. 
Please, help!

I have a solution for you.
Called MS Support and they told me that sharepoint tries to send these mails authenticated via the Web Appl Pool Account.
So we started netmon to analyse this problem.
There we found the entry:
SMTP:Rsp 550  5.7.1 Client does not have permissions to send as this sender
You can solve this problem by authorizing the Web Appl Pool User to the SMTP receive connector (on exchange server):
Get-ReceiveConnector “<spconector>” | Add-ADPermission -User “CONTOSO\AppPoolAccount” -ExtendedRights “ms-Exch-SMTP-Accept-Authoritative-Domain-Sender”
Get-ReceiveConnector “<spconector>” | Add-ADPermission -User “CONTOSO\AppPoolAccount” -ExtendedRights “ms-Exch-SMTP-Accept-Any-Sender”
or (this is what we do):
Add the IP addresses of the sharepoint webservers to the relay of the exchange servers (for this you must have an open relay connector).

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