STMP problem : check email settings

Hello,
I am trying to use the smtp demo to send email through my work account how ever i am encountering this error
SMTP SEND FAILED:
Command: MAIL FROM:<DSSOUTBOUND@DSSopen1>
RetCode: 551
Response: 551 Sender address is not valid for your login. Check your email program settings.
the settings i have in outlook is
outgoing mail server is : mail.synergize.ca
and the port is 25,
the code i am using to invoke the stmp is
{"-d","-M","mail.synergize.ca","-U","wrivers","-P","****","-A","-s","Overdue leads"," [email protected]"};
is there a problem with my code or is it to do with the server ?

Well, the From address for your message (DSSOUTBOUND)
and the user name you're using to login with (wrivers)
don't match, and that may be what your server is
complaining about. The protocol trace might provide
more information about what the server is complaining
about.
If that is indeed the problem, and you believe you
should have permission to send such messages,
you're going to have to reconfigure your server
appropriately. (And no, I don't know how to tell you
to do that.)

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