I was trying to find out if the PCI-DIO-32​HS will take thermocoup​le readings?

I have a PCI-DIO-32HS and a SCB-68 connector block. I am trying to figure out if the card will receive the input coming from a thermocouple.

Dennis is right.
however, if you feel like not spending more money on a analog input board, and have hands for a little electronics, here what you can do:
1) use a 16bit D/A converter (eg DAC7744), connected to the card.
2) connect the output to a comparator (LM311),  to compare with your own analog input. you might want to isolate the 2 inputs via INA105.
3) connect the output via a pull up resistor directly to pin 1 of your parallel port.
4) create a small Labview program for making a 16 (or 8 or 4) bit comparison process:
       - create an analog value of 0V (via 16 bit digital card)
       - check if response is true or false (higher or lower than your  analog in) from the parallel port
       - if true, send new analog value of -5V
....check again, 16 times.
you got your analog value. of course this is a relatively slow process, as you have to read the parallel before each time you send the new analog value. yet, it is going to be much faster than a NI-USB 6008 for example. i expect a rate around the KHz at least.
... And here's where I keep assorted lengths of wires...

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