Issues opening xml files in CS6

I'm having a problem opening xml files in CS6. Currently, I'm able to load Dreamweaver CS6, but when I open a file labeled as .xml, the application freezes up. I have already set up my preferences to read .xml files. (some background info: I do have a previous version of 5.5 installed on the same machine. I could guess that the problem could be associated with having an earlier version of dreamweaver installed at the same time, but why would it only affect xml files?)

Have you tried opening the .xml file in NotePad or some other simple text editor? just to verify that the file is good and not corrupted.

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