Issues publishing links to Office 2010 applications

I have a Windows Server 2008 R2 with SharePoint 2010 installed, Windows 7 64Bit Enterprise clients, Office 2010 x86.  It has been in production for close to 2 years.  At first, the main function was to archive email with vital documents for projects,
RFPs and legal information.  Now, we are moving closer with another department using it straight from Word/Excel and wanting to save from Office applications.  I have been working on getting the links published but I have not had much luck. 
I got it to work once several months ago when I had to re-build the User profile service and Mysites.  Now, getting it to work again is my problem.  The links that was published at first only went to me and a couple other people and they were still
there today.  This is my problem now:  When I use the All Site Users audience to publish a link to either a site or doc library, nothing is pushed.  I can create a new audience and test with it and nothing happens.  When I go in and clear
out the registry key on my client machine that has the Mysites personal page information in it, reboot the machine and then delete the "SharePoint Sites" folder from my user profile and then publish the link, it works.  I cannot publish any
NEW links.  If I publish something new, it never shows up in the folder.  Also, I have read that Desktop Experience needs to be turned on for this to work.  DE is not turned on but yet I can still publish the one link and I can also use the
"Open in Explorer" button in SP with IE11.  Also, the Web Client service is running on the client machine if that makes a difference. 
Why can I not make more than one link?  Do I really need to turn on DE on the server? 
David Hood

For a shorter question, why does only the first link that I publish work and none after that?
David Hood
UPDATE:  I have re-tested this and it seems that I cannot get a new link to show up in my list unless I either delete the registry keys, restart and then delete the Sharepoint List folder and go back to MySites for it to ask to connect to Office, or Manually
adding another document library through the web browser.   When I manually add another library/list to Office via the Connect To Office button, my other links that I published from the server show up. 

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    Remove
    alert
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    We are on windows environment as below - 
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    Have you found anything in event Viewer?
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    In fact, none of the Microsoft Office 2010 applications have any capability of opening PDF files.
    For Microsoft Office 2013, Word does have an ability to open PDF files, creating a Word document from same. That having been said, the fidelity of such conversions is very poor, especially when any graphics are involved.
    Alternatively, Acrobat does provide a means of exporting PDF files to Word, Excel, and PowerPoint formats with the caveat that you will likely need to do editing of the result for meaningful use. The results are certainly much better than can be achieved by Word 2013's PDF opening capability!
                - Dov

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