SMTP Error in Mail

I have just gone from PC to Mac and Input all my email details into Mail. It is a private domian with my own server so I know that it is functioning perfectly fine.
It is an IMAP account and works fine on a PC but with mail i get an SMTP Error. It just doesn't send the mail and remains offline.
Any ideas anyone?
Thanks
Tim

Update: ok so this does appear to be a bug with mail in that you can't unselect SSL. The only way I found to get round it is to immediately restart after deselecting it. You'll then need to do this for each account that isn't working it appears.

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