Exchange 2003 users are unable to send attachments larger then 8 MB to Exchange 2010 users on the same LAN

I am migrating from Exchange 2003 to Exchange 2010.
Users who are still on Exchange 2003 cannot send attachments any larger than around 8MB to Exchange 2010 users on the same LAN.
Users on Exchange 2010 can send large attachments to fellow Exchange 2010 users without issue.
I do not have any quota restrictions on Exchange 2010.
Had a look at the Exchange 2003 Connector but could not see any reference to attachement restrictions.
Has anyone come across this?

Here is a note of the NDR:-
Your message did not reach some or all of the intended recipients.
Subject:   
The following recipient(s) cannot be reached:
Tracey xxxxxx on 01/12/2014 13:27
This message is larger than the current system limit or the recipient's mailbox is full. 
Create a shorter message body or remove attachments and try sending it again.
<mail.xxxxxxxxx.com #5.2.3 smtp;450 5.2.3 Msg Size greater than allowed by Remote Host>

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