Sqlplus not connecting through application user

Hi ,
I have R12 instance
DB Version : 11.2.0.3
App Version : 12.1.1
Here i am able to connect apps user from DB user But when trying to connect from application user we are getting the below error, Please help.
From DB user :
*[oradev@dev ~]$ sqlplus apps/apps145*
SQLPlus: Release 11.2.0.3.0 Production on Sat Apr 13 23:44:32 2013*
Copyright (c) 1982, 2011, Oracle. All rights reserved.
Connected to:
Oracle Database 11g Enterprise Edition Release 11.2.0.3.0 - 64bit Production
With the Partitioning, OLAP, Data Mining and Real Application Testing options
SQL> exit
From Application User :
*[appldev@dev ~]$ sqlplus apps/apps145*
SQLPlus: Release 10.1.0.5.0 - Production on Sat Apr 13 23:44:43 2013*
Copyright (c) 1982, 2005, Oracle. All rights reserved.
ERROR:
ORA-12154: TNS:could not resolve the connect identifier specified
Enter user-name:
Regards
Rajesh T

Here i am able to connect apps user from DB user But when trying to connect from application user we are getting the below error, Please help.
From DB user :
*[oradev@dev ~]$ sqlplus apps/apps145*
SQLPlus: Release 11.2.0.3.0 Production on Sat Apr 13 23:44:32 2013*
Copyright (c) 1982, 2011, Oracle. All rights reserved.
Connected to:
Oracle Database 11g Enterprise Edition Release 11.2.0.3.0 - 64bit Production
With the Partitioning, OLAP, Data Mining and Real Application Testing options
SQL> exit
From Application User :
*[appldev@dev ~]$ sqlplus apps/apps145*
SQLPlus: Release 10.1.0.5.0 - Production on Sat Apr 13 23:44:43 2013*
Copyright (c) 1982, 2005, Oracle. All rights reserved.
ERROR:
ORA-12154: TNS:could not resolve the connect identifier specified
Is the database listener up and running?
Can you connect to the database remotely (from your client machine)?
What is the output of "echo $ORACLE_SID" and "echo $TWO_TASK" return as applmgr user after sourcing the application env file (APPS<CONTEXT_NAME>.env under $APPL_TOP directory)?
Thanks,
Hussein

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